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Which of the following equations is obtained on combining 1st and 2nd law of thermodynamics, for a system of constant mass ?

Which of the following equations is obtained on combining 1st and 2nd law of thermodynamics, for a system of constant mass ?

A. dE = Tds – PdV
B. dQ = CvdT + PdV
C. dQ = CpdT + Vdp
D. Tds = dE – PdV